Coordination polymers containing 1,3-Phenylenebis-((1H-1,2,4-triazol-1-yl)methanone) ligand: Synthesis and "-caprolactone polymerization behavior
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Fecha
2017-11
Profesor/a Guía
Facultad/escuela
Idioma
en
Título de la revista
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Título del volumen
Editor
MDPI AG
Nombre de Curso
Licencia CC
CC BY 4.0 DEED
Licencia CC
https://creativecommons.org/licenses/by/4.0/deed.es
Resumen
The reaction of isophthaloyl dichloride with 1H-1,2,4-triazole afforded the new ligand 1,3-phenylenebis(1,2,4-triazole-1-yl)methanone (1). A series of Co(II), Cu(II), Zn(II) and Ni(II) complexes were synthesized using 1 and then characterized by melting point analysis, elemental analysis, theoretical calculations, thermogravimetric analysis, X-ray powder diffraction, nuclear magnetic resonance, infrared and Raman spectroscopy. Experimental and computational studies predict the formation of coordination polymers (CPs). The cobalt and copper CPs and zinc(II) complex were found to be good initiators for the ring-opening polymerization of "-caprolactone (CL) under solvent-free conditions. 1H-NMR analysis showed that the obtained polymers of CL were mainly linear and had terminal hydroxymethylene groups. Differential scanning calorimetry showed that the obtained polycaprolactones had high crystallinity, and TGA showed that they had decomposition temperatures above 400 C. These results provide insight and guidance for the design of metal complexes with potential applications in the polymerization of CL. © 2017 by the authors.
Notas
Indexación: Scopus
Palabras clave
Caprolactone Polymerization, Coordination Polymers, Initiators, Triazole Ligand
Citación
Molecules Volume 22, Issue 11November 2017 Article number 1860
DOI
10.3390/molecules22111860