First copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis
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Fecha
2015-07
Profesor/a Guía
Facultad/escuela
Idioma
en
Título de la revista
ISSN de la revista
Título del volumen
Editor
Royal Society of Chemistry
Nombre de Curso
Licencia CC
Atribución-NoComercial 3.0 Chile (CC BY-NC 3.0 CL)
Licencia CC
https://creativecommons.org/licenses/by-nc/3.0/cl/
Resumen
M′0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M′ = CoII, NiII, CuII, ZnII), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3. © The Royal Society of Chemistry.
Notas
Indexación: Scopus
Palabras clave
Phosphorothioic Acid, Selenophosphate, Magnetism
Citación
Dalton Transactions Volume 44, Issue 28, Pages 12493 - 1249628 July 2015
DOI
10.1039/c5dt01540e