Occurrence and air-water diffusive exchange legacy persistent organic pollutants in an oligotrophic north Patagonian lake

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Fecha
2022-03
Profesor/a Guía
Facultad/escuela
Idioma
en
Título de la revista
ISSN de la revista
Título del volumen
Editor
Academic Press Inc.
Nombre de Curso
Licencia CC
Atribución/Reconocimiento-NoComercial-SinDerivados 4.0 Internacional CC BY-NC-ND 4.0 Deed
Licencia CC
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
Resumen
In this study, the occurrence and diffusive air-water exchange of POPs in Panguipulli Lake (39°42′S-72°13′W), an oligotrophic lake located in northern Patagonia (Chile), were determined. Air and water samples were collected between March and August 2017 (autumn-winter) and analyzed for concentrations of OCPs (α-HCH, β-HCH, γ-HCH and HCB) and PCBs (PCB-28,-52,-101,-118,-153,-158,-180) using gas chromatography coupled with an electron capture detector. The direction of air-water exchange direction was evaluated using a fugacity approach (ƒw ƒa−1), and net diffusive exchange fluxes (FAW, ng m−2 d−1) were also estimated. Total ∑4OCP levels in air ranged from 0.31 to 37 pg m−3, with a maximum for β-HCH, while Σ7PCB levels ranged from 3.05 to 43 pg m−3. The most abundant congener was PCB-153, accounting for 60% of the total PCBs in air. Surface water ∑4OCPs measured in this study ranged from 1.01 to 3.9 pg L−1, with γ-HCH predominating, while surface water Σ7PCB levels ranged from 0.32 to 24 pg L−1, with PCB-101, PCB-118, and PCB-153 presenting the highest levels. Diffusive air-water exchanges of HCB, α-HCH, γ-HCH and PCBs in the form of volatilization from the lake to air predominated; in contrast, for β-HCH net deposition dominated during the sampling period. Estimates suggested faster microbial degradation in the dissolved phase compared to atmospheric degradation for all analyzed POPs. Overall, these results could indicate that the oligotrophic lakes of northern Patagonia act as a secondary source of atmospheric POPs, mainly PCBs and some OCPs. This study is a first attempt to understand the occurrence of POPs in air and water, as well as their dynamics in oligotrophic lakes in the southern hemisphere. © 2021
Notas
Indexación: Scopus.
Palabras clave
Air-water exchange, Legacy pollutants, North patagonian lakes, Pesticides, South America
Citación
Environmental Research, Volume 204, March 2022, Article number 112042
DOI
10.1016/j.envres.2021.112042
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