(Acetyl-acetonato)dibromido[2,2-diphenyl-hydrazin-1-ido(1-)][2, 2-diphenyl-hydrazin-1-ido(2-)]molybdenum(VI)
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Archivos
Fecha
2011-06
Profesor/a Guía
Facultad/escuela
Idioma
en
Título de la revista
ISSN de la revista
Título del volumen
Editor
International Union of Crystallography
Nombre de Curso
Licencia CC
Attribution 2.0 UK: England & Wales (CC BY 2.0 UK)
Licencia CC
https://journals.iucr.org/services/oa/openaccess_e.html
Resumen
In the title compound, [MoBr2(C12H11N 2)(C12H10N2)(C5H 7O2)], the MoVI atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from the diphenyl-hydrazide(1-) and diphenyl-hydrazide(2-) ligands, two O atoms from a bidentate acetyl-acetonate ligand and two Br- ions. The mol-ecules form an inversion dimer via a pair of weak C - H⋯O hydrogen bonds and a π-π stacking inter-action with a centroid-centroid distance of 3.7401 (12) Å. Weak intra-molecular C - H⋯Br inter-actions and an intra-molecular π-π stacking inter-action with a centroid-centroid distance of 3.8118 (15) Å are also observed.
Notas
Indexación: Scopus.
Palabras clave
Nitrogen, Nitrides, Molybdenum
Citación
Acta Crystallographica Section E: Structure Reports Online, Volume 67, Issue 6, Pages m675-m676, June 2011
DOI
10.1107/S1600536811015881