ZrO2-supported alkali metal (Li, Na, K) catalysts for biodiesel production

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Miniatura
Fecha
2016
Profesor/a Guía
Facultad/escuela
Idioma
en
Título de la revista
ISSN de la revista
Título del volumen
Editor
Sociedad Chilena de Quimica
Nombre de Curso
Licencia CC
Licencia CC
Resumen
We studied the effect of the alkali metal type (Li, Na, and K) and the calcination temperature (500, 600 and 700 °C) in the activity for biodiesel production of catalysts prepared by impregnation method, with constant metal content of 10%w/w using ZrO2 as support. The results of the catalytic activity allowed to find an activity sequence regarding the alkali tested metals: Na > Li > K, with this sequence remaining constant independent of the calcination temperature. The high activity of the Na/ZrO2 system, and slightly lower activity of Li/ZrO2 , can be explained by the fact that higher calcination temperatures promote the formation of alkali-based zirconate species, M2 ZrO3 (M = Na or Li). The presence of these species is correlated with the higher activity of these catalysts, specifically with the Na and Li-based catalyst calcined at high temperatures (600-700 °C). These M2 ZrO3 species show higher basicity respect to other alkali metal oxide species, as was demonstrated with CO2 -TPD results. The higher activity corresponded to 10% Na supported on ZrO2 and calcined at 700 °C, which reached full conversion within just 30 minutes of reaction, which makes this system a promising heterogeneous replacement for the regular homogeneous systems.
Notas
Indexación: Scopus.
Palabras clave
Alkali Metal, Zirconia, Heterogeneous Catalysts, Transesterification, Biodiesel
Citación
Journal of the Chilean Chemical Society. Volume 61, Issue 4, Pages 3233 - 3238. 2016
DOI
10.4067/S0717-97072016000400017
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