First copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

Fuentealba, PabloCortés, CatalinaAudebrand, NathalieLe Fur, EricParedes-García, VerónicaVenegas-Yazigi, DiegoManzur, JorgeSpodine, Evgenia2023-04-052023-04-052015-07Dalton Transactions Volume 44, Issue 28, Pages 12493 - 1249628 July 20151477-9226https://repositorio.unab.cl/xmlui/handle/ria/48243Indexación: ScopusM′0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M′ = CoII, NiII, CuII, ZnII), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3. © The Royal Society of Chemistry.enPhosphorothioic AcidSelenophosphateMagnetismFirst copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesisArtículoAtribución-NoComercial 3.0 Chile (CC BY-NC 3.0 CL)10.1039/c5dt01540e