(Acetyl-acetonato)dibromido[2,2-diphenyl-hydrazin-1-ido(1-)][2, 2-diphenyl-hydrazin-1-ido(2-)]molybdenum(VI)

Bustos, C.Alvarez-Thon, L.Ibãez, A.Sánchez, C.2023-08-082023-08-082011-06Acta Crystallographica Section E: Structure Reports Online, Volume 67, Issue 6, Pages m675-m676, June 20111600-5368https://repositorio.unab.cl/xmlui/handle/ria/52308Indexación: Scopus.In the title compound, [MoBr2(C12H11N 2)(C12H10N2)(C5H 7O2)], the MoVI atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from the diphenyl-hydrazide(1-) and diphenyl-hydrazide(2-) ligands, two O atoms from a bidentate acetyl-acetonate ligand and two Br- ions. The mol-ecules form an inversion dimer via a pair of weak C - H⋯O hydrogen bonds and a π-π stacking inter-action with a centroid-centroid distance of 3.7401 (12) Å. Weak intra-molecular C - H⋯Br inter-actions and an intra-molecular π-π stacking inter-action with a centroid-centroid distance of 3.8118 (15) Å are also observed.enNitrogenNitridesMolybdenum(Acetyl-acetonato)dibromido[2,2-diphenyl-hydrazin-1-ido(1-)][2, 2-diphenyl-hydrazin-1-ido(2-)]molybdenum(VI)ArtículoAttribution 2.0 UK: England & Wales (CC BY 2.0 UK)10.1107/S1600536811015881