Examinando por Autor "Aguila, G."

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    Activity of alumina supported fe catalysts for N2O decomposition: Effects of the iron content and thermal treatment
    (Sociedad Chilena de Quimica, 2017) Alvarez, P.; Araya, P.; Rojas, R.; Guerrero, S.; Aguila, G.
    The activity of Fe2O3/Al2O3 catalysts prepared by impregnation of Al2O3 with different amounts of Fe and calcination temperatures (650 and 900 °C) in the direct N2O decomposition reaction was studied. High calcination temperature was introduced to study the effect of "aging", which are the conditions prevailing in the process-gas option for N2O abatement. The catalysts were characterized by BET, XRD, UV-DRS, and H2-TPR. The incorporation of Fe promotes the alumina phase transition (g-Al2O3 to a-Al2O3) when the catalysts are calcined at 900 °C, which is accompanied by a decrease in the specifc area. The activity of the catalysts and the specifc surface area depend on Fe loading and calcination temperature. It was found that highly dispersed Fe species are more active than bulk type Fe2O3 particles. We conclude that Fe2O3/Al2O3 catalysts prepared by impregnation method are active in the decomposition of N2O, to be used at low or high reaction temperatures (tail-gas or process-gas treatments, respectively), as part of nitric acid production plant. © 2018 Sociedad Chilena de Quimica. All rights reserved.
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    Ítem
    Design and feasibility study for the evaluation of an Agrovoltaics generation system: Case of Temuco in Chile
    (Elsevier, 2024) Latorre, P.; Amigo, L.; Gatica, G.; Aguila, G.; Vidal-Pacheco, L.; Coronado-Hernández, J.
    Chile is a country that has had large renewable energy resources in recent years, and it has demonstrated a commitment to the use of clean energy. However, most solar energy projects are located in northern Chile, neglecting other areas, such as the southern part of the country, where the photovoltaic energy industry has the potential to thrive. This is the case in the Araucanía region, particularly in Temuco, which has diverse agricultural activity. However, being a remote area without access to the electrical grid, it relies on generation sources like oil. This article, a research product, aims to demonstrate the functionality that can be added to agricultural land by combining it with solar parks. To achieve this, an agrovoltaic system was estimated for a plot of land in the agricultural zone of Temuco. This system will serve as a sample of the integration between photovoltaic infrastructure and the agricultural industry for those interested in installing it.
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    Thermal stability of the cu-ceo2 interface on silica and alumina, and its relation with activity in the oxidation reaction of co and the decomposition of n2o
    (Sociedad Chilena de Quimica, 2018) Alvarez, P.; Aguila, G.; Guerrero, S.; Araya, P.
    The effect of the support on the formation of the Cu-CeO2 interface and its thermal stability after calcination at 500, 700 and 900 °C is studied. The supports used are SiO2, because of its inert character, and Al2O3, because it can interact with the Cu and Ce species on the surface. The catalysts were characterized by BET, XRD, UV-vis DRS, and TPR with H2. The catalytic activity in the CO oxidation reactions with O2 at low temperature and the decomposition of N2O were selected to visualize the effect of temperature on the concentration of Cu-CeO2 interfacial sites. The results show that at a calcination temperature of 500 °C the formation of the Cu-CeO2 interface is favored over the SiO2 support. However, the stability of the Cu-CeO2 interface on SiO2 is much lower than on Al2O3, causing a substantial decrease of the interfacial sites calcining at 700 °C, and segregation of the Cu and Ce species on the surface of the silica, with complete loss of the catalytic activity in both reactions when calcining at 900 °C. In contrast, on alumina the Cu-CeO2 interface is more stable and presents a significant catalytic activity in both reactions, even when calcining at 900 °C. The characterization results show that the sintering process of Cu species and CeO2 particles is less on the alumina support due to the greater interaction of the Cu and Ce with this support. © 2018 Sociedad Chilena de Quimica.all rights reserved.