Study of cyclic metal-ligand complexes containing closed-shell coinage metals : formation and consequence of bonding interactions between the d10-d10 centers
dc.contributor.advisor | Muñoz Castro, Álvaro | |
dc.contributor.author | Guajardo Maturana, Raúl. | |
dc.contributor.editor | Facultad de Ciencias Exactas | |
dc.date.accessioned | 2022-06-30T18:32:05Z | |
dc.date.available | 2022-06-30T18:32:05Z | |
dc.date.issued | 2015 | |
dc.description | Tesis (Doctor en Fisicoquímica Molecular) | es |
dc.description.abstract | Supramolecular chemistry has attracted the attention of several research groups due to it constitutes a significant step toward the design and development of molecular devices and new materials. In materials science, functional complexes containing monovalent Au(I), Ag(I), Cu(I) metal ions with d1º closed-shell interactions exhibit an interesting set of properties related to supramolecular aggregation, such as photoluminescence, catalysis, molecular magnetism, making them suitable for to a wide variety of technological application. We focus on multimetallic system, where several closed-shell metal centers are stabilized with organic ligand, leading to a two dimensional core of three or more metallic atoms linked to sigma-donor ligands involving both metal-metal and metalligand interactions, retaining the metallic core. | es |
dc.identifier.uri | https://repositorio.unab.cl/xmlui/handle/ria/23093 | |
dc.language.iso | en | es |
dc.publisher | Universidad Andrés Bello | es |
dc.subject | Complejos de Metales, Compuestos Macrocíclicos. | es |
dc.title | Study of cyclic metal-ligand complexes containing closed-shell coinage metals : formation and consequence of bonding interactions between the d10-d10 centers | es |
dc.type | Tesis | es |
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