Mulinane and azorellane diterpenoid biomarkers by GC-MS from a representative Apiaceae (Umbelliferae) species of the Andes

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dc.contributor.authorSimoneit, Bernd R.T.
dc.contributor.authorOros, Daniel R.
dc.contributor.authorJaffé, Rudolf
dc.contributor.authorDidyk-Peña, Alexandra
dc.contributor.authorAreche, Carlos
dc.contributor.authorSepúlveda, Beatriz
dc.contributor.authorDidyk, Borys M.
dc.date.accessioned2023-03-30T20:23:56Z
dc.date.available2023-03-30T20:23:56Z
dc.date.issued2019-02
dc.descriptionIndexación: Scopuses
dc.description.abstractExtracts of bled resin from Azorella compacta, of the Azorelloideae family from the Andes (>4000 m), were analyzed by gas chromatography-mass spectrometry. The mass spectra of the dominant compounds of the resin and its hydrogenation products were documented. The most abundant compounds were oxygenated diterpenoids, namely mulinadien-20-oic (∆11,13 and ∆11,14) acids, azorell-13-en-20-oic acid, 13α,14β-dihydroxymulin-11-en-20-oic acid, and azorellanol, with a group of azorellenes and mulinadienes. The mass spectra of the novel diterpenoid hydrocarbons with the azorellane and mulinane skeletons were also presented. This study documents the molecular diversity of these diterpenoid classes, and could be of great utility for future organic geochemical, environmental, archeological, pharmaceutical, and forensic chemistry studies. © 2019 by the authors.es
dc.description.urihttps://www.mdpi.com/1420-3049/24/4/684
dc.identifier.citationMolecules Volume 24, Issue 414 February 2019 Article number 684es
dc.identifier.doi10.3390/molecules24040684
dc.identifier.issn1420-3049
dc.identifier.urihttps://repositorio.unab.cl/xmlui/handle/ria/48070
dc.language.isoenes
dc.publisherMDPIes
dc.rights.licenseAtribución 4.0 Internacional (CC BY 4.0)
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/deed.es
dc.subjectAzorella compactaes
dc.subjectDiterpenoidses
dc.subjectGC-MSes
dc.subjectStandardses
dc.titleMulinane and azorellane diterpenoid biomarkers by GC-MS from a representative Apiaceae (Umbelliferae) species of the Andeses
dc.typeArtículoes
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