Oxidative degradations of the side chain of unsaturated Ent-labdanes. Part II

dc.contributor.author	Catalán, L.E.
dc.contributor.author	Marín, K.C.
dc.contributor.author	Altamirano H.C.
dc.contributor.author	Fritis, M.C.
dc.contributor.author	Chamy M.C.
dc.date.accessioned	2021-06-22T15:20:31Z
dc.date.available	2021-06-22T15:20:31Z
dc.date.issued	2007-12
dc.description	Indexación: Scopus.	es
dc.description.abstract	A route for the degradation of the side chain of ent-labdane derivatives has been devised, giving the useful synthon 2β,12-dihydroxy-13,14,15,16,17- pentanor-ent-labdane-8-one (8). The use of this compound in the preparation of terpenylquinone derivatives shall be reported elsewhere. In addition we have synthesized the compound 2β,12-diacetoxy-8β,17-epoxy-13,14,15,16- tetranor-ent-labdane (10), which upon catalytic epoxide ring opening in alkaline or acid media gave rise in all cases to the formation of tricyclic compounds. © 2007 by MDPI.	es
dc.description.uri	https://www.mdpi.com/1420-3049/12/12/2605
dc.identifier.citation	MoleculesOpen AccessVolume 12, Issue 12, Pages 2605 - 2620December 2007	es
dc.identifier.doi	10.3390/12122605
dc.identifier.issn	1420-3049
dc.identifier.uri	http://repositorio.unab.cl/xmlui/handle/ria/19148
dc.language.iso	en	es
dc.publisher	MDPI	es
dc.subject	Ent-labdanes	es
dc.subject	Selective degradations	es
dc.subject	Unsaturated side chain	es
dc.title	Oxidative degradations of the side chain of unsaturated Ent-labdanes. Part II	es
dc.type	Artículo	es

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