STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]

dc.contributor.authorVENEGAS, FELIPE
dc.contributor.authorPIZARRO, NANCY
dc.contributor.authorVEGA, ANDRES
dc.date.accessioned2016-07-19T16:30:25Z
dc.date.available2016-07-19T16:30:25Z
dc.date.issued2011
dc.descriptionIndexación: Web of Science; Scieloes
dc.description.abstractWe have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br] by direct reaction of (Re(CO)3Br(THF))2 and the ligand (C6H5)2(C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rhenium octahedral environment. The molecule displays an absorption band centered at 315 nm which has been assigned to a MLCT transition, and a luminescence quantum yield of 0.001.es
dc.description.urihttp://ref.scielo.org/ptnngv
dc.identifier.citationJ. Chil. Chem. Soc. vol.56 no.3 Concepción 2011es
dc.identifier.issn0717-9707
dc.identifier.otherhttp://dx.doi.org/10.4067/S0717-97072011000300023
dc.identifier.urihttp://repositorio.unab.cl/xmlui/handle/ria/1100
dc.language.isoenes
dc.publisherSociedad Chilena de Químicaes
dc.subjectChemistryes
dc.titleSTRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]es
dc.typeArtículoes
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