STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]
dc.contributor.author | VENEGAS, FELIPE | |
dc.contributor.author | PIZARRO, NANCY | |
dc.contributor.author | VEGA, ANDRES | |
dc.date.accessioned | 2016-07-19T16:30:25Z | |
dc.date.available | 2016-07-19T16:30:25Z | |
dc.date.issued | 2011 | |
dc.description | Indexación: Web of Science; Scielo | es |
dc.description.abstract | We have prepared a new monometallic rhenium(I) carbonyl, the complex [P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br] by direct reaction of (Re(CO)3Br(THF))2 and the ligand (C6H5)2(C5H5N)P The structure in the complex shows the pyridinic-phosphine ligand in a chelating mode, occupying cis positions around the rhenium octahedral environment. The molecule displays an absorption band centered at 315 nm which has been assigned to a MLCT transition, and a luminescence quantum yield of 0.001. | es |
dc.description.uri | http://ref.scielo.org/ptnngv | |
dc.identifier.citation | J. Chil. Chem. Soc. vol.56 no.3 Concepción 2011 | es |
dc.identifier.issn | 0717-9707 | |
dc.identifier.other | http://dx.doi.org/10.4067/S0717-97072011000300023 | |
dc.identifier.uri | http://repositorio.unab.cl/xmlui/handle/ria/1100 | |
dc.language.iso | en | es |
dc.publisher | Sociedad Chilena de Química | es |
dc.subject | Chemistry | es |
dc.title | STRUCTURAL AND PHOTOPHYSICAL PROPERTIES OF A MONONUCLEAR Re(I) COMPLEX:[P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br] | es |
dc.type | Artículo | es |
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