Azide-Based High-Energy Metal-Organic Frameworks with Enhanced Thermal Stability

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dc.contributor.authorChi-Duran, Ignacio
dc.contributor.authorEnríquez, Javier
dc.contributor.authorManquian, Carolina
dc.contributor.authorFritz, Ruben Alejandro
dc.contributor.authorVega, Andres
dc.contributor.authorSerafini, Daniel
dc.contributor.authorHerrera, Felipe
dc.contributor.authorSingh, Dinesh Pratap
dc.date.accessioned2023-06-12T19:58:03Z
dc.date.available2023-06-12T19:58:03Z
dc.date.issued2019-09-10
dc.descriptionIndexación Scopuses
dc.description.abstractWe describe the structure and properties of [Zn(C6H4N5)N3]n, a new nonporous three-dimensional high-energy metal-organic framework (HE-MOF) with enhanced thermal stability. The compound is synthesized by the hydrothermal method with in situ ligand formation under controlled pH and characterized using single-crystal X-ray diffraction, elemental analysis, and Fourier transform infrared. The measured detonation temperature (Tdet = 345 °C) and heat of detonation (Î"Hdet =-0.380 kcal/g) compare well with commercial explosives and other nitrogen-rich HE-MOFs. The velocity and pressure of denotation are 5.96 km/s and 9.56 GPa, respectively. Differential scanning calorimetry analysis shows that the denotation of [Zn(C6H4N5)N3]n occurs via a complex temperature-dependent mechanism.es
dc.identifier.citationACS Omega Volume 4, Issue 11, Pages 14398 - 14403 10 September 2019es
dc.identifier.doi10.1021/acsomega.9b01127en
dc.identifier.issn2470-1343
dc.identifier.urihttps://repositorio.unab.cl/xmlui/handle/ria/50589
dc.language.isoenes
dc.publisherACS Omegaes
dc.titleAzide-Based High-Energy Metal-Organic Frameworks with Enhanced Thermal Stabilityes
dc.typeArtículoes
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