Semi-empirical algorithm for estimation of calorimetric properties in binary liquid mixtures from acoustic and volumetric data

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dc.contributor.authorMeza, M.
dc.contributor.authorCantero-López, P.
dc.contributor.authorSotelo, D.
dc.date.accessioned2022-08-05T14:10:13Z
dc.date.available2022-08-05T14:10:13Z
dc.date.issued2022-02
dc.descriptionIndexación: Scopus.es
dc.description.abstractIn the present work, a semi-empirical algorithm is proposed for estimating the adiabatic coefficient (γ), the isothermal compressibility (κτ), the heat capacity at constant pressure (cp), and constant volume (cv), for liquid mixtures of organic compounds as a function of temperature and concentration. The algorithm was applied to the binary systems: 1,6-Dichlorohexene (x) + Dodecane (1-x) and 1,5-Dichloropentane (x) + Dodecane (1-x) reported in literature. The obtaining values for γ, cp, cv and κτ are reported at all concentrations and temperatures. The implementation of the algorithm required experimental data of the adiabatic coefficients of the pure components (γi0) to 298.15 K, acoustic and volumetric data of the binary mixture in the entire concentration and temperature range between (278.15–328.15) K every 5 K. The results obtained are in excellent agreement with the experimental results.es
dc.description.urihttps://www-sciencedirect-com.recursosbiblioteca.unab.cl/science/article/pii/S1018364721004523?via%3Dihub
dc.identifier.citationJournal of King Saud University - Science, Volume 34, Issue 2, February 2022, Article number 101790es
dc.identifier.doi10.1016/j.jksus.2021.101790
dc.identifier.issn1018-3647
dc.identifier.urihttps://repositorio.unab.cl/xmlui/handle/ria/23461
dc.language.isoenes
dc.publisherElsevier B.V.es
dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
dc.rights.urihttps://s100.copyright.com/AppDispatchServlet?publisherName=ELS&contentID=S1018364721004523&orderBeanReset=true
dc.subjectAdiabatic coefficientes
dc.subjectHeat capacityes
dc.subjectIsobaric expansibilityes
dc.subjectIsothermal compressibilityes
dc.subjectSemi-empirical algorithmes
dc.subjectSpeed of soundes
dc.titleSemi-empirical algorithm for estimation of calorimetric properties in binary liquid mixtures from acoustic and volumetric dataes
dc.typeArtículoes
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