Hexaaquazinc(II) dinitrate bis[5-(pyridinium-3-yl)tetrazol-1-ide]

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dc.contributor.authorChi-Duran, I.
dc.contributor.authorEnriquez, J.
dc.contributor.authorVega, A.
dc.contributor.authorHerrera, F.
dc.contributor.authorSingh, D.P.
dc.date.accessioned2019-12-05T19:17:56Z
dc.date.available2019-12-05T19:17:56Z
dc.date.issued2018
dc.descriptionIndexación: Scopus.es
dc.descriptionFunding for this research was provided by: Fondecyt Regular (award No. 1151527); Proyecto REDES ETAPA INICIAL, Convocatoria 2017 (award No. REDI170423); Millennium Institute for Research in Optics (MIRO); Basal USA (award No. 1799).
dc.description.abstractHexaaquazinc(II) dinitrate 5-(pyridinium-3-yl)tetrazol-1-ide, [Zn(H2 O)6](NO 3)2 ·2C6H5 N 5, crystallizes in the space group P. The asymmetric unit contains one zwitterionic 5-(pyridinium-3-yl)tetrazol-1-ide molecule, one NO3-anion and one half of a [Zn(H2 O)6]2+ cation (symmetry). The pyridinium and tetrazolide rings in the zwitterion are nearly coplanar, with a dihedral angle of 5.4 (2)°. Several O-H..N and N-H..O hydrogen-bonding interactions exist between the [Zn(H2 O)6]2+ cation and the N atoms of the tetrazolide ring, and between the nitrate anions and the N-H groups of the pyridinium ring, respectively, giving rise to a three-dimensional network. The 5-(pyridinium-3-yl)tetrazol-1-ide molecules show parallel-displaced π-π stacking interactions; the centroid-centroid distance between adjacent tetrazolide rings is 3.6298 (6) Å and that between the pyridinium and tetrazolide rings is 3.6120 (5) Å. © 2018 Chi-Duran et al.es
dc.description.urihttp://journals.iucr.org/e/issues/2018/09/00/cq2025/index.html
dc.identifier.issn2056-9890
dc.identifier.otherDOI: 10.1107/S205698901801112X
dc.identifier.urihttp://repositorio.unab.cl/xmlui/handle/ria/11197
dc.language.isoenes
dc.publisherInternational Union of Crystallographyes
dc.subjectCrystal stryucturees
dc.subjectHexaaquazinc(II) complexes
dc.subjectHydrogen-bondinges
dc.subjectPyridin-3-yltetrazolees
dc.subjectπ-π stackinges
dc.titleHexaaquazinc(II) dinitrate bis[5-(pyridinium-3-yl)tetrazol-1-ide]es
dc.typeArtículoes
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