Crystal structure and Hirshfeld surface analysis of tris(2,2′-bipyridine)nickel(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate
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Archivos
Fecha
2019
Profesor/a Guía
Facultad/escuela
Idioma
en
Título de la revista
ISSN de la revista
Título del volumen
Editor
Acta Crystallographica Section E: Crystallographic Communications
Nombre de Curso
Licencia CC
Licencia CC
Resumen
The title compound, [Ni(C10H8N2)3](C9H5N4O)2 2H2O, crystallizes as a racemic
mixture in the monoclinic space group C2/c. In the crystal, the 1,1,3,3-
tetracyano-2-ethoxypropenide anions and the water molecules are linked by
O—H N hydrogen bonds, forming chains running along the [010] direction.
The bpy ligands of the cation are linked to the chain via C—H (cation)
interactions involving the CH3 group. The intermolecular interactions were
investigated by Hirshfeld surface analysis and two-dimensional fingerprint plots.
Notas
Indexación Scopus
Palabras clave
crystal structure, Hirshfeld surface analysis, hydrogen bonding, polynitrile ligand
Citación
Acta Crystallographica Section E: Crystallographic Communications Volume 75, Pages 867 - 871 2019
DOI
10.1107/S2056989019006959